Structural and dynamical heterogeneities in two-dimensional melting

Using molecular dynamics simulation, we study structural and dynamical heterogeneities at melting in two-dimensional one-component systems with 36000 particles. Between crystal and liquid we find intermediate hexatic states, where the density fluctuations are enhanced at small wave number k as well as those of the six-fold orientational order parameter. Their structure factors both grow up to the smallest wave number equal to the inverse system length. The intermediate scattering function of the density S(k,t) is found to relax exponentially with decay rate Gamma_k ~ k^z with z~2.6 at small k in the hexatic phase.Comment: 6 pages, 8 figure

Spreading with evaporation and condensation in one-component fluids

We investigate the dynamics of spreading of a small liquid droplet in gas in a one-component simple fluid, where the temperature is inhomogeneous around 0.9Tc and latent heat is released or generated at the interface upon evaporation or condensation (with Tc being the critical temperature). In the scheme of the dynamic van der Waals theory, the hydrodynamic equations containing the gradient stress are solved in the axisymmetric geometry. We assume that the substrate has a finite thickness and its temperature obeys the thermal diffusion equation. A precursor film then spreads ahead of the bulk droplet itself in the complete wetting condition. Cooling the substrate enhances condensation of gas onto the advancing film, which mostly takes place near the film edge and can be the dominant mechanism of the film growth in a late stage. The generated latent heat produces a temperature peak or a hot spot in the gas region near the film edge. On the other hand, heating the substrate induces evaporation all over the interface. For weak heating, a steady-state circular thin film can be formed on the substrate. For stronger heating, evaporation dominates over condensation, leading to eventual disappearance of the liquid region.Comment: 12 pages, 14 figure

Plastic flow in polycrystal states in a binary mixture

Using molecular dynamics simulation we examine dynamics in sheared polycrystal states in a binary mixture containing 10% larger particles in two dimensions. We find large stress fluctuations arising from sliding motions of the particles at the grain boundaries, which occur cooperatively to release the elastic energy stored. These dynamic processes are visualized with the aid of a sixfold angle $\alpha_j(t)$ representing the local crystal orientation and a disorder variable $D_j(t)$ representing a deviation from the hexagonal order for particle $j$.Comment: 3 pages, 3 figure

Self-organization in He4 near the superfluid transition in heat flow and gravity

We investigate the nonlinear dynamics of He4 slightly below the superffluid transition by integrating model F equations in three dimensions. When heated from above under gravity, a vortex tangle and a sheetlike phase slip are generated near the bottom plate. Then a self-organized superfluid containing high-density vortices and phase slips grows upward into an ordinary superfluid. The thermal resistance due to these defects produces a constant temperature gradient equal to the gradient of the pressure-dependent transition temperature $T_{\lambda}(p)$. In this self-organized region, the temperature deviation $T-T_{\lambda}(p)$ consists of a negative constant independent of the height and time-dependent fluctuations. Its time-average is calculated in good agreement with the experimental value (W.A. Moeur {\it et al.}, Phys. Rev. Lett. 78, 2421 (1997)).Comment: 8 pages, 7 figure

Phase transition in compressible Ising systems at fixed volume

Using a Ginzburg-Landau model, we study the phase transition behavior of compressible Ising systems at constant volume by varying the temperature $T$ and the applied magnetic field $h$. We show that two phases can coexist macroscopically in equilibrium within a closed region in the $T$-$h$ plane. It occurence is favored near tricriticality. We find a field-induced critical point, where the correlation length diverges, the difference of the coexisting two phases and the surface tension vanish, but the isothermal magnetic susceptibility does not diverge in the mean field theory. We also investigate phase ordering numerically.Comment: 13 figure

Dynamics of Binary Mixtures with Ions: Dynamic Structure Factor and Mesophase Formation

Dynamic equations are presented for polar binary mixtures containing ions in the presence of the preferential solvation. In one-phase states, we calculate the dynamic structure factor of the composition accounting for the ion motions. Microphase separation can take place for sufficiently large solvation asymmetry of the cations and the anions. We show two-dimensional simulation results of the mesophase formation with an antagonistic salt, where the cations are hydrophilic and the anions are hydrophobic. The structure factor S(q) in the resultant mesophase has a sharp peak at an intermediate wave number on the order of the Debye-Huckel wave number. As the quench depth is increased, the surface tension nearly vanishes in mesophases due to an electric double layer.Comment: 24 pages, 10 figures, to appear in Journal of Physics: Condensed Matte

Thermoacoustic effects in supercritical fluids near the critical point: Resonance, piston effect, and acoustic emission and reflection

We present a general theory of thermoacoustic phenomena in supercritical fluids near the critical point in a one-dimensional cell. We take into account the effects of the heat conduction in the boundary walls and the bulk viscosity near the critical point. We introduce a coefficient $Z(\omega)$ characterizing reflection of sound with frequency $\omega$ at the boundary. As applications, we examine the acoustic eigenmodes in the cell, the response to time-dependent perturbations, sound emission and reflection at the boundary. Resonance and rapid adiabatic changes are noteworthy. In these processes, the role of the thermal diffusion layers is enhanced near the critical point because of the strong critical divergence of the thermal expansion.Comment: 15 pages, 7 figure

Intermediate states at structural phase transition: Model with a one-component order parameter coupled to strains

We study a Ginzburg-Landau model of structural phase transition in two dimensions, in which a single order parameter is coupled to the tetragonal and dilational strains. Such elastic coupling terms in the free energy much affect the phase transition behavior particularly near the tricriticality. A characteristic feature is appearance of intermediate states, where the ordered and disordered regions coexist on mesoscopic scales in nearly steady states in a temperature window. The window width increases with increasing the strength of the dilational coupling. It arises from freezing of phase ordering in inhomogeneous strains. No impurity mechanism is involved. We present a simple theory of the intermediate states to produce phase diagrams consistent with simulation results.Comment: 16 pages, 14 figure

Dynamic van der Waals Theory of two-phase fluids in heat flow

We present a dynamic van der Waals theory. It is useful to study phase separation when the temperature varies in space. We show that if heat flow is applied to liquid suspending a gas droplet at zero gravity, a convective flow occurs such that the temperature gradient within the droplet nearly vanishes. As the heat flux is increased, the droplet becomes attached to the heated wall that is wetted by liquid in equilibrium. In one case corresponding to partial wetting by gas, an apparent contact angle can be defined. In the ther case with larger heat flux, the droplet completely wets the heated wall expelling liquid.Comment: 6pages, 8figure